Electrochemical Performance of Deposited LiPON Film/Lithium Electrode in Lithium-Sulfur Batteries.

This paper presents a composed lithium phosphate (LiPON) solid electrolyte interface (SEI) film which was coated on a lithium electrode via an electrodeposit method in a lithium-sulfur battery, and the structure of the product was characterized through infrared spectrum (IR) analysis, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), environment scanning electron microscope (ESEM), etc. Meanwhile, the electrochemical impedance spectrum and the interface stability of the lithium electrode with the LiPON film was analyzed, while the coulomb efficiency and the cycle life of the lithium electrode with the LiPON film in the lithium-sulfur battery were also studied. It was found that this kind of film can effectively inhibit the charge from transferring at the interface between the electrode and the solution, which can produce a more stable interface impedance on the electrode, thereby improving the interface contact with the electrolyte, and effectively improve the discharge performance, cycle life, and the coulomb efficiency of the lithium-sulfur battery. This is of great significance for the further development of solid electrolyte facial mask technology for lithium-sulfur batteries.