Fully Biobased Photothermal Films and Coatings for Indoor Ultraviolet Radiation and Heat Management.

Sustainable materials are needed to mitigate against the increase in energy consumption resulting from population growth and urbanization. Here, we report fully biobased nanocomposite films and coatings that display efficient photothermal activity and selective absorption of ultraviolet (UV) radiation. The nanocomposites with 20 wt % of lignin nanoparticles (LNPs) embedded in a chitosan matrix displayed an efficient UV blocking of 97% at 400 nm along with solar energy-harvesting properties. The reflectance spectra of the nanocomposite films revealed the importance of well-dispersed nanoparticles in the matrix to achieve efficient UV-blocking properties. Finally, yet importantly, we demonstrate the nanocomposites with 20 wt % LNPs as photothermal glass coatings for passive cooling of indoor temperature by simply tailoring the coating thickness. Under simulated solar irradiation of 100 mW/cm 2 , the 20 μm coating achieved a 58% decrease in the temperature increment in comparison to the system with uncoated glass. These renewable nanocomposite films and coatings are highly promising sustainable solutions to facilitate indoor thermal management and improve human health and well-being.