Carboxymethyl Cellulose/Copper Oxide-Titanium Oxide Based Nanocatalyst Beads for the Reduction of Organic and Inorganic Pollutants.

In this work, we have developed novel beads based on carboxymethyl cellulose (CMC) encapsulated copper oxide-titanium oxide (CuO-TiO 2 ) nanocomposite (CMC/CuO-TiO 2 ) via Al +3 cross-linking agent. The developed CMC/CuO-TiO 2 beads were applied as a promising catalyst for the catalytic reduction of organic and inorganic contaminants; nitrophenols (NP), methyl orange (MO), eosin yellow (EY) and potassium hexacyanoferrate (K 3 [Fe(CN) 6 ]) in the presence of reducing agent (NaBH 4 ). CMC/CuO-TiO 2 nanocatalyst beads exhibited excellent catalytic activity in the reduction of all selected pollutants (4-NP, 2-NP, 2,6-DNP, MO, EY and K 3 [Fe(CN) 6 ]). Further, the catalytic activity of beads was optimized toward 4-nitrophenol with varying its concentrations and testing different concentrations of NaBH 4 . Beads stability, reusability, and loss in catalytic activity were investigated using the recyclability method, in which the CMC/CuO-TiO 2 nanocomposite beads were tested several times for the reduction of 4-NP. As a result, the designed CMC/CuO-TiO 2 nanocomposite beads are strong, stable, and their catalytic activity has been proven.