Cyclopentadienyl capped thorium(IV) porphyrinoid complex.
Daniel N MangelJames T BrewsterGabriel J JuarezVincent M LynchJonathan L SesslerPublished in: Chemical communications (Cambridge, England) (2024)
The reaction between Th(IV) dipyriamethyrin dichloride and sodium cyclopentadienyl (Cp) results in the formation of a cyclopentadienyl capped thorium dipyriamethyrin complex, which to our knowledge represents the first expanded porphyrin f-element Cp complex.