C-HCl- hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands.

Mari IkedaAjay Kumar SahMiki IwaseRina MurashigeJun-Ichi Ishi-IMasatoshi HasegawaChihiro Kachi-TerajimaKi-Min ParkShunsuke KuwaharaYoichi Habata

Published in: Dalton transactions (Cambridge, England : 2003) (2018)

Structural evidence is reported for C-HCl- hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl2 complex contains an acetonitrile molecule in the cavity.

Keyphrases

solid state
high resolution
amino acid
biofilm formation
dual energy
escherichia coli
mass spectrometry
pseudomonas aeruginosa
cystic fibrosis