Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework.

A rapid surface sealing strategy has been developed for the encapsulation of a homogeneous catalyst, phosphotungstic acid (PTA), in a mesoporous metal-organic framework (MOF), MIL-101(Cr). This new surface polymerization method utilizes non-solvent-induced phase separation to concentrate and direct polyamine and dianhydride monomers onto MOF particle surfaces, thus realizing the formation of a sub-10 nm, uniform, and cross-linked polymer coating within a few seconds. While fully preserving the catalytic activity of the neat PTA for the catalytic decomposition of phenol, the surface-sealed PTA-MOF composite catalyst can be reused up to 10 times with no noticeable loss of activity and negligible leaching of PTA. Since this surface coating method is not limited by either the MOF or the catalyst, it will become the technique of choice for the immobilization of homogeneous catalysts in MOFs.