Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes.

Frédéric A PerrasAlejandra ArroyaveScott A Southern Jessica V Lamb Yuting Li Anne M LaPointe Massimiliano Delferro

Published in: Chemical communications (Cambridge, England) (2023)

Obtaining three-dimensional (3D) configurational information of surface organometallic complexes is a persistent challenge due to the low spatial sensitivity of most spectroscopic methods. We show that employing 17 O-enriched supports enables highly informative multidimensional NMR experiments, including radial and vertical distance measurements, that can be used to elucidate site geometry.

Keyphrases

magnetic resonance
high resolution
solid state
health information
molecular docking
energy transfer
single cell
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molecular dynamics simulations
quantum dots