Kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cages.
Pieter J GilissenQuentin DuezGuilherme L TripodiMagda M J DekkerJiangkun OuyangKais DhbaibiNicolas VanthuyneJeanne CrassousJana RoithováJohannes A A W ElemansRoeland J M NoltePublished in: Chemical communications (Cambridge, England) (2023)
The kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cage compounds, measured in terms of ΔΔ G ‡on, is determined by the planar-chirality of the host and influenced by the size, as measured by ion mobility-mass spectrometry, but not the chirality of its substituents.