Electrifying the transport sector is crucial for reducing CO 2 emissions and achieving Paris Agreement targets. This largely depends on rapid decarbonization in power plants; however, we often overlook the trade-offs between reduced transportation emissions and additional energy-supply sector emissions induced by electrification. Here, we developed a framework for China's transport sector, including analyzing driving factors of historical CO 2 emissions, collecting energy-related parameters of numerous vehicles based on the field- investigation, and assessing the energy-environment impacts of electrification policies with national heterogeneity. We find holistic electrification in China's transport sector will cause substantial cumulative CO 2 emission reduction (2025-2075), equivalent to 19.8-42% of global annual emissions, but with a 2.2-16.1 GtCO 2 net increase considering the additional emissions in energy-supply sectors. It also leads to a 5.1- to 6.7-fold increase in electricity demand, and the resulting CO 2 emissions far surpass the emission reduction achieved. Only under 2 and 1.5 °C scenarios, forcing further decarbonization in the energy supply sectors, will the holistic electrification of transportation have a robust mitigation effect, -2.5 to -7.0 Gt and -6.4 to -11.3 Gt net-negative emissions, respectively. Therefore, we conclude that electrifying the transport sector cannot be a one-size-fits-all policy, requiring synergistically decarbonization efforts in the energy-supply sectors.