A microporous Zr 6 @Zr-MOF for the separation of Xe and Kr.
Fu-An GuoKang ZhouJiaqi LiuXingyu LiHao WangPublished in: Dalton transactions (Cambridge, England : 2003) (2022)
We report here the self-assembly of a she -type zirconium-based metal-organic framework with discrete hexanuclear Zr-oxo clusters residing inside its pore windows. The overall structure features microporosity showing preferential adsorption of Xe over Kr.