Anthracene-Argon Clusters Generated in Superfluid Helium Nanodroplets: New Aspects on Cluster Formation and Microsolvation.

About two decades after extensive studies on anthracene-Arn clusters in the gas phase, we report corresponding studies in superfluid helium droplets. With AN as a small fluorophore and spectroscopic data from the gas phase and helium droplets, both the formation of clusters and the microsolvation in superfluid helium droplets can be studied. As expected for helium droplets, a significantly higher number of isomeric variants of the respective cluster sizes are obtained, because metastable variants are stabilized by the low temperature and the surrounding helium. Moreover, spectroscopic data recorded in helium droplets reveal cluster configurations with Ar atoms shielded by a helium solvation layer. Surprisingly, AN-Arn clusters with more than four Ar atoms do not appear to form rigid configurations. The helium droplet data in combination with the gas phase spectra may serve as a suitable reference for further theoretical investigations on solvation and cluster formation in superfluid helium droplets.