Deformation-Induced Phase Transformations in Gold Nanoribbons with the 4H Phase.

The mechanical stability of metallic nanomaterials has been intensively studied due to their unique structures and promising applications. Although extensive investigations have been carried out on the deformation behaviors of metallic nanomaterials, the atomic-scale deformation mechanism of metallic nanomaterials with unconventional hexagonal structures remains unclear because of the lack of direct experimental observation. Here, we conduct an atomic-resolution in situ tensile-straining transmission electron microscopy investigation on the deformation mechanism of gold nanoribbons with the 4H (hexagonal) phase. Our results reveal that plastic deformation in the 4H gold nanoribbons comprises three stages, in which both full and partial dislocations are involved. At the early deformation stage, plastic deformation is governed by full dislocation activities. Partial dislocations are subsequently activated in regions that have undergone full dislocation gliding, leading to phase transformation from the 4H phase to the face-centered cubic (FCC) phase. At the last stage of the deformation process, the volume fraction of the FCC phase increases, and full dislocation activities in the FCC regions also play an important role.