Double-stranded metallo-triangles: from anion-templated nonanuclear to cation-templated tetraicosanuclear dysprosium clusters.
Yanan LiuXiao SunPeiqiong ChenXiaojuan LiFu-Ping HuangHou-Ting LiuHaiquan TianPublished in: Chemical communications (Cambridge, England) (2023)
Two double-stranded metallo-triangles, Dy9 and Dy24, with hexaple-C 10 H 7 PO 3 2- bridges were constructed, and their magnetic properties were explored. Compared with the field-induced relaxation phenomenon of Dy9 templated with a chloride anion, Dy24 templated with a sodium cation exhibited zero-field single-molecule-magnet behavior.