Generation and study of Am(IV) by temperature-controlled electron pulse radiolysis.
Amy E KynmanTravis S GrimesStephen P MezykBobby LayneAndrew R CookBrian M RotermundGregory P HornePublished in: Dalton transactions (Cambridge, England : 2003) (2024)
First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(IV) in concentrated (6.0 M) HNO 3 , and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO 3 ˙ and Am(III).