Fabrication of polyhedral Cu-Zn oxide nanoparticles by dealloying and anodic oxidation of German silver alloy for photoelectrochemical water splitting.

A significant effort has been dedicated to the synthesis of Cu-Zn oxide nanoparticles as a robust photocathode material for photoelectrochemical water splitting. Cu-Zn oxide nanoparticles were formed by controlled anodization of German silver (Cu-Zn-Ni) alloy in an aqueous electrolyte. Scanning electron microscopy (SEM) demonstrates the dependence of the obtained nanostructures on the anodization time. The X-ray diffraction (XRD) patterns showed the formation of copper oxide (CuO) and zinc oxide (ZnO) nanoparticles with good stability. This was also confirmed by the compositional X-ray photoelectron spectroscopy (XPS) analysis. The obtained polyhedral nanoparticles showed high optical activity with adequate bandgap energy. These optimized nanoparticles achieved boosted photocurrent of - 0.55 mA/cm 2 at - 0.6 V vs. SCE under AM 1.5 illumination, confirming the role of the optimized dealloying and thermal treatment in tuning the photoelectrochemical performance of the material.