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Monodisperse MoS 2 /Graphite Composite Anode Materials for Advanced Lithium Ion Batteries.

Baosheng LiuFeng LiHongda LiShaohui ZhangJinghua LiuXiong HeZijun SunZhiqiang YuYujin ZhangXiaoqi HuangFei GuoGuofu WangXiaobo Jia
Published in: Molecules (Basel, Switzerland) (2023)
Traditional graphite anode material typically shows a low theoretical capacity and easy lithium decomposition. Molybdenum disulfide is one of the promising anode materials for advanced lithium-ion batteries, which possess low cost, unique two-dimensional layered structure, and high theoretical capacity. However, the low reversible capacity and the cycling-capacity retention rate induced by its poor conductivity and volume expansion during cycling blocks further application. In this paper, a collaborative control strategy of monodisperse MoS 2 /graphite composites was utilized and studied in detail. MoS 2 /graphite nanocomposites with different ratios (MoS 2 :graphite = 20%:80%, 40%:60%, 60%:40%, and 80%:20%) were prepared by mechanical ball-milling and low-temperature annealing. The graphite sheets were uniformly dispersed between the MoS 2 sheets by the ball-milling process, which effectively reduced the agglomeration of MoS 2 and simultaneously improved the electrical conductivity of the composite. It was found that the capacity of MoS 2 /graphite composites kept increasing along with the increasing percentage of MoS 2 and possessed the highest initial discharge capacity (832.70 mAh/g) when MoS 2 :graphite = 80%:20%. This facile strategy is easy to implement, is low-cost, and is cosmically produced, which is suitable for the development and manufacture of advance lithium-ion batteries.
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