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Electrochemical oxidative C-H/S-H cross-coupling between enamines and thiophenols with H2 evolution.

Dandan LiShuaibing LiChong PengLijun LuShengchun WangPan WangYi-Hung ChenHengjiang CongAiwen Lei
Published in: Chemical science (2019)
Electrochemical oxidative C-H/S-H cross-coupling has been developed to construct the C-S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strategy not only avoided the use of chemical oxidants and transition metal catalysts, but also exhibited excellent atom economy.
Keyphrases
  • transition metal
  • gold nanoparticles
  • molecularly imprinted
  • ionic liquid
  • label free
  • electron transfer
  • single cell
  • cell therapy
  • molecular dynamics
  • fluorescent probe
  • high resolution
  • liquid chromatography