Salicylaldehydate coordinated two-dimensional-conjugated metal-organic frameworks.
Abdul Khayum MohammedPilar Pena-SánchezAjmal PandikassalaSafa GaberAyesha A AlKhooriTina SkorjancKyriaki PolychronopoulouSreekumar KurungotFelipe GándaraDinesh ShettyPublished in: Chemical communications (Cambridge, England) (2023)
A novel class of copper-based 2D-c-MOF was synthesized from 1,3,5-triformylphloroglucinol using green mechano-chemistry. Herein, metal coordination with the salicylaldehyde functional moiety was explored for the first time in MOFs. Moreover, an intrinsic semiconductive copper-based SA-MOF thin film was fabricated using an in situ salt-free method at room temperature.