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WO3 Nanoarray: An Efficient Electrochemical Oxygen Evolution Catalyst Electrode Operating in Alkaline Solution.

Xuqiang JiMin MaRuixiang GeXiang RenHui WangJingquan LiuZhiang LiuAbdullah Mohammed AsiriXuping Sun
Published in: Inorganic chemistry (2017)
It is fascinating to design and synthesize high-efficiency and noble-metal-free alkaline oxygen evolution reaction (OER) electrocatalysts. In this Communication, we describe the one-step hydrothermal synthesis of a WO3 nanoarray directly grown on conductive carbon cloth (WO3/CC) for efficient water oxidation in 1.0 M KOH. As a monolithically integrated array catalyst, WO3/CC exhibits superior OER activity demanding overpotential as low as 280 mV to afford a benchmarking catalytic current density of 10 mA cm-2. It is worth noting that WO3/CC also possesses strong electrochemical durability with 95% Faradaic yields.
Keyphrases
  • visible light
  • ionic liquid
  • high efficiency
  • gold nanoparticles
  • reduced graphene oxide
  • room temperature
  • molecularly imprinted
  • electron transfer
  • mass spectrometry
  • hydrogen peroxide
  • crystal structure