A diarsene radical anion.

Grégoire SiegMalte FischerFabian DankertJan-Erik SiewertChristian Hering-Junghans C Gunnar Werncke

Published in: Chemical communications (Cambridge, England) (2022)

The isolation of the first diarsene radical anion by reduction of a neutral diarsene is presented. Comprehensive characterisation in conjunction with DFT calculations reveals unpaired spin density residing in the antibonding π*-orbital with involvement of the terphenyl ligands. First reactivity studies reveal no pronounced radical, but rather reducing properties.

Keyphrases

density functional theory
ionic liquid
molecular dynamics
genome wide
single cell
dna methylation