Pd-Catalyzed Stereoselective 1,2-Aryboration of Alkenylarenes.
Penglin ZhangMimi XingQitao GuanJinguo ZhangQian ZhaoChun ZhangPublished in: Organic letters (2019)
The palladium-catalyzed highly regio- and diastereoselective arylboration of alkenylarenes has been developed. This chemistry afforded the benzylic boronic esters with a broad substrate scope, which are valuable synthetic intermediates for organic synthesis. The chiral anion phase-transfer strategy was designed for this transformation to realize the regio-, diastereo-, and enantioselective control of this reaction simultaneously.