Pressure-Temperature Phase Diagram Reveals Spin-Lattice Interactions in Co[N(CN)2]2.

Janice L MusfeldtK R O'NealT V BrinzariP ChenJ A SchlueterJ L MansonA P LitvinchukZ Liu

Published in: Inorganic chemistry (2017)

Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure-temperature phase diagram of Co[N(CN)2]2. The second-order structural boundaries converge on key areas of activity involving the spin state exposing how the pressure-induced local lattice distortions trigger the ferromagnetic → antiferromagnetic transition in this quantum material.

Keyphrases

density functional theory
room temperature
molecular dynamics
single cell
lymph node metastasis
single molecule
high glucose
cell therapy
genome wide
molecular dynamics simulations
squamous cell carcinoma
gene expression
oxidative stress
transition metal
endothelial cells
label free