Rheological and Thermal Conductivity Study of Two-Dimensional Molybdenum Disulfide-Based Ethylene Glycol Nanofluids for Heat Transfer Applications.

The rheological behavior of two-dimensional (2D) MoS 2 -based ethylene glycol (EG) nanofluids (NFs) was investigated at low volume concentrations (0.005%, 0.0075%, and 0.01%) in a wide temperature range of 0-70 °C and at atmospheric pressure. A conventional two-step method was followed to prepare NFs at desired volume concentrations. Based on the control rotational (0.1-1000 s -1 shear rate) and oscillation (0.01-1000% strain) methods, the viscoelastic flow curves and thixotropic (3ITT (three interval thixotropic) and hysteresis loop) characteristics of NFs were examined. Shear flow behavior revealed a remarkable reduction (1.3~14.7%) in apparent dynamic viscosity, which showed concentration and temperature dependency. Such remarkable viscosity results were assigned to the change in activation energy of the ethylene glycol with the addition of MoS 2 . However, the nanofluids exhibited Newtonian behavior at all temperatures for concentrations below 0.01% between 10 and 1000 s -1 . On the other hand, strain sweep (@1Hz) indicated the viscoelastic nature of NFs with yielding, which varied with concentration and temperature. Besides, 3ITT and hysteresis loop analysis was evident of non-thixotropic behavior of NFs. Among all tested concentrations, 0.005% outperformed at almost all targeted temperatures. At the same time, ~11% improvement in thermal conductivity can be considered advantageous on top of the improved rheological properties. In addition, viscosity enhancement and reduction mechanisms were also discussed.