N-Heterocyclic silylenes in coinage metal chemistry: an account of recent advances.

This article intends to highlight and comprehensively summarize the recent developments in the field of silylene-coinage metal chemistry. Recent years have witnessed exponential growth in the utilization of N-heterocyclic silylenes as ligands in transition metal chemistry. Still, silylene-coinage metal complexes have only started to appear very recently. Particular attention is focused on the synthetic approaches to silylene-coinage metal complexes and their unusual properties derived from the spectroscopic and crystallographic data. Recent studies have demonstrated that silylene-coinage metal complexes exhibit catalytic efficiency towards hydrosilylation, copper-catalyzed alkyne azide cycloaddition (CuAAC), and glycosidation reactions. Although the chemistry of silylene-coinage metal complexes has only begun to blossom, these findings justify the need for a review at this stage of development. This article will summarize the previous work on silylene-coinage metal complexes followed by recent advances and conclude with future possibilities.