Electrostatic force on a spherical particle confined between two planar surfaces.
Zhanwen WangMichael J MiksisPetia M VlahovskaPublished in: Soft matter (2023)
A charge-free particle in a uniform electric field experiences no net force in an unbounded domain. A boundary, however, breaks the symmetry and the particle can be attracted or repelled to it, depending on the applied field direction [Z. Wang et al. , Phys. Rev. E , 2022, 106 , 034607]. Here, we investigate the effect of a second boundary because of its common occurrence in practical applications. We consider a spherical particle suspended between two parallel walls and subjected to a uniform electric field, applied in a direction either normal or tangential to the surfaces. All media are modeled as leaky dielectrics, thus allowing for the accumulation of free charge at interfaces, while bulk media remain charge-free. The Laplace equation for the electric potential is solved using a multipole expansion and the boundaries are accounted for by a set of images. The results show that in the case of a normal electric field, which corresponds to a particle between two electrodes, the force is always attractive to the nearer boundary and, in general, weaker that the case of only one wall. Intriguingly, for a given particle-wall separation we find that the force may vary nonmonotonically with confinement and its magnitude may exceed the one-wall value. In the case of tangential electric field, which corresponds to a particle between insulating boundaries, the force follows the same trends but it is always repulsive.