Air-tolerant upconverted circularly polarized luminescence enabled by confined space of chiral micelle.

Circularly polarized luminescence (CPL) has been widely demonstrated that the circular polarization in excited state can be significantly amplified through the triplet-triplet annihilation-based upconversion (TTA-UC) luminescence process in various chiral nano-assemblies. However, constructing such an upconverted circularly polarized luminescence (UC-CPL) system in the aqueous phase remains a challenge. In this work, a kind of amphiphilic chiral cationic gemini surfactant is utilized to construct chiral spherical micelle in the aqueous phase, whose internal chiral cavity can provide a hydrophobic and deoxygenated environment for air-sensitive TTA-UC system. In addition, due to the co-assembly process between the emitters and chiral micelles, achiral emitters of upconversion pairs exhibit induced chiroptical properties. More importantly, the luminescence dissymmetry factor (g lum ) can be amplified by one order of magnitude through TTA-UC process. This work provides an effective and useful strategy for realizing UC-CPL in aqueous phase.