Interplanar Ferromagnetism Enhanced Ultrawide Zero Thermal Expansion in Kagome Cubic Intermetallic (Zr,Nb)Fe 2 .
Yanming SunYili CaoShixin HuMaxim AvdeevChin-Wei WangSergii KhmelevskyiYang RenSaul H LapidusXin ChenQiang LiJinxia DengJun MiaoKun LinXiao-Jun KuangXianran XingPublished in: Journal of the American Chemical Society (2023)
A cubic metal exhibiting zero thermal expansion (ZTE) over a wide temperature window demonstrates significant applications in a broad range of advanced technologies but is extremely rare in nature. Here, enabled by high-temperature synthesis, we realize tunable thermal expansion via magnetic doping in the class of kagome cubic ( Fd -3 m ) intermetallic (Zr,Nb)Fe 2 . A remarkably isotropic ZTE is achieved with a negligible coefficient of thermal expansion (+0.47 × 10 -6 K -1 ) from 4 to 425 K, almost wider than most ZTE in metals available. A combined in situ magnetization, neutron powder diffraction, and hyperfine Mössbauer spectrum analysis reveals that interplanar ferromagnetic ordering contributes to a large magnetic compensation for normal lattice contraction upon cooling. Trace Fe-doping introduces extra magnetic exchange interactions that distinctly enhance the ferromagnetism and magnetic ordering temperature, thus engendering such an ultrawide ZTE. This work presents a promising ZTE in kagome metallic materials.