Using solid-state nuclear magnetic resonance to rationalize best efficiency of 2,6-dihydroxybenzoic acid over other 2,X-dihydroxybenzoic acid isomers in solvent-free matrix-assisted laser desorption/ionization of poly(ethylene glycol).

Complementary data in 13 C, 7 Li, and 19 F NMR spectra are consistent with the formation of a solid phase of high mobility composed of 2,6-DHB, PEG, and the two salt components that ultimately favor the production of lithiated PEG chains.