Turn-on Fluorescent Detection of Hydrogen Peroxide and Triacetone Triperoxide via Enhancing Interfacial Interactions of a Blended System.

In this work, we report the fabrication of a blend consisting of fluorescent 1 nanofibers and amberlyst-15 particles as a turn-on fluorescence sensor for trace TATP vapors. Fluorescence imaging and lifetime analysis reveal that the interface between 1 nanofibers and amberlyst-15 particles exhibits stronger photoluminescence than the unblended areas because of the formed strong hydrogen bonding between. Furthermore, the interfacial adhesion between 1 nanofibers and amberlyst-15 particles can be amplified by H2O2, which in turn gives rise to rapid and remarkable fluorescence enhancement. When exposed to TATP vapors, the amberlyst-15 component can rapidly decompose TATP into H2O2 that gives sensitive fluorescence enhancement responses of the blend. On the basis of this detection mechanism, fluorescence detection of TATP with rapid response (ca. 5 s) and high sensitivity (ca. 0.1 ppm) is achieved. Here, the resulting blend combines the pretreatment of TATP and detection responses and thereby simplifies the senor fabrication for the practical application.