A facile one-step hydrothermal approach to synthesize hierarchical core-shell NiFe 2 O 4 @NiFe 2 O 4 nanosheet arrays on Ni foam with large specific capacitance for supercapacitors.

In this contribution, NiFe 2 O 4 @NiFe 2 O 4 nanosheet arrays (NSAs) with three-dimensional (3D) hierarchical core-shell structures were synthesized by a facile one-step hydrothermal method and they were used as electrode materials for supercapacitors (SCs). The NiFe 2 O 4 @NiFe 2 O 4 composite electrode showed a high specific capacitance of 1452.6 F g -1 (5 mA cm -2 ). It also exhibited a superior cycling stability (93% retention after 3000 cycles). Moreover, an asymmetric supercapacitor (ASC) was constructed utilizing NiFe 2 O 4 @NiFe 2 O 4 NSAs and activated carbon (AC) as the positive and negative electrode, respectively. The optimized ASC shows extraordinary performances with a high energy density of 33.6 W h kg -1 at a power density of 367.3 W kg -1 and an excellent cycling stability of 95.3% capacitance retention over 3000 cycles. Therefore, NiFe 2 O 4 @NiFe 2 O 4 NSAs have excellent pseudocapacitance properties and are good electrode materials for high energy density.