Coaxial Nanofiber IrO x @SbSnO x as an Efficient Electrocatalyst for Proton Exchange Membrane Dehumidifier.

Development of efficient catalysts for oxygen evolution reaction (OER) remains challenging in PEM dehumidifier or vapor electrolyzer. This study developed novel coaxial IrO x @SbSnO x nanofiber (NF) catalysts by electrospinning using a dual-channel needle. This method ensures the fibrous structure and the uniform loading of Ir oxide on the support of antimony tin oxide (ATO). IrO 2 @SbSnO x nanoparticles were synthesized for comparison. Characterizations showed that the active area and charge transfer resistance of NF was 1.47 times and 17.72% of that of commercial ones, respectively. The overpotential of NF at 10 mA·cm -2 was 359 mV, much smaller than that of commercial IrO 2 (418 mV). In addition, the reaction overpotential of NF increased by only 38 mV after 1000 cyclic voltammetry cycles, indicating good electrochemical stability. To explore the enhancement mechanism, first-principles calculations were conducted for theoretically simulating the hetero-structures. Based on d-band theory, the structure formed between ATO and IrO 2 can effectively weaken the adsorption of oxygen intermediates on the catalyst surface, which reduces the OER energy barrier from 1.705 to 1.632 eV, causing an over 15% decrease of overpotential after loading on ATO. As a practical attempt, we applied the new catalysts in real PEM assembly for air dehumidification and found that the performance was improved by about 2 times compared with that using commercial catalysts. This study provides a research direction for the design of one-dimensional NF catalysts and their using in PEM applications.