Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex.

Xiao-Peng SunZheng TangJiajia LiPengtao MaZi-Shuo YaoJingping WangJingyang Niu Jun Tao

Published in: Inorganic chemistry (2022)

Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.

Keyphrases

small molecule
optical coherence tomography
high resolution
high throughput
reduced graphene oxide
electron microscopy
metal organic framework
high speed