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Absence of 3a 0 charge density wave order in the infinite-layer nickelate NdNiO 2 .

Christopher T ParzyckNaman K GuptaY WuV AnilL BhattM BoulianeR GongB Z GregoryA LuoRonny SutartoFeizhou HeY-D ChuangT ZhouG HerranzL F KourkoutisAndrej SingerDarrell G SchlomD G HawthornKyle M Shen
Published in: Nature materials (2024)
A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a 0 charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO 2+x samples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO 2 . The 3a 0 superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO 2 highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors.
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