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[1,2-Bis(diiso-propyl-phosphan-yl)ethane-κ 2 P , P '](2-fluoro- N -{[(2-fluoro-phen-yl)aza-nid-yl]carbon-yl}anilinido-κ 2 N , N ')nickel(II).

Marcos Flores-AlamoFrancisco J Perez-OrtizAlma ArevaloJuventino J García
Published in: IUCrData (2020)
The mol-ecular structure of the title complex, [Ni(C 13 H 8 F 2 N 2 O)(C 14 H 32 P 2 )] or Ni(oFPU)(dippe), where oFPU is the dianion of bis-(2-fluoro-phen-yl)urea and dippe is 1,2-bis-(di-iso-propyl-phosphino)ethane, comprises an Ni II atom with a distorted square-planar coordination environment (geometry index τ 4 = 0.195). One of the fluoro-phenyl rings of the oFPU ligand is disordered over two sets of sites in an 0.832 (7):0.168 (7) ratio. The crystal structure displays C-H⋯O and C-H⋯F hydrogen-bonding inter-actions, leading to chains with R 2 2 (12) motifs extending parallel to [100]. The title compound might be of inter-est with respect to the production of urea and carbamate derivatives of nickel(II).
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