Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes.
Pei ZhaoJiaxin HuangJie LiKezhuo ZhangWen YangWanxiang ZhaoPublished in: Chemical communications (Cambridge, England) (2021)
The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.