Light-Mediated Polymerization Induced by Semiconducting Nanomaterials: State-of-the-Art and Future Perspectives.

Direct capture of solar energy for chemical transformation via photocatalysis proves to be a cost-effective and energy-saving approach to construct organic compounds. With the recent growth in photosynthesis, photopolymerization has been established as a robust strategy for the production of specialty polymers with complex structures, precise molecular weight, and narrow dispersity. A key challenge in photopolymerization is the scarcity of effective photomediators (photoinitiators, photocatalysts, etc.) that can provide polymerization with high yield and well-defined polymer products. Current efforts on developing photomediators have mainly focused on organic dyes and metal complexes. On the other hand, nanomaterials (NMs), particularly semiconducting nanomaterials (SNMs), are suitable candidates for photochemical reactions due to their unique optical and electrical properties, such as high absorption coefficients, large charge diffusion lengths, and broad absorption spectra. This review provides a comprehensive insight into SNMs' photomediated polymerizations and highlights the roles SNMs play in photopolymerizations, types of polymerizations, applications in producing advanced materials, and the future directions.