Selective Electrochemical Oxidation of Functionalized Pyrrolidines.

Nicholas R DeprezDane J ClausenJia-Xuan YanFeng PengShaoguang ZhangJongrock KongYanguang Bai

Published in: Organic letters (2021)

A method for the selective electrochemical aminoxyl-mediated Shono-type oxidation of pyrrolidines to pyrrolidinones is described. These transformations show the high selectivity and functional group compatibility. This chemistry also demonstrates the use of an operationally simple ElectraSyn 2.0 and cost-effective stainless-steel electrode for the electrochemical oxidation of functionalized pyrrolidines.

Keyphrases

molecularly imprinted
electron transfer
gold nanoparticles
hydrogen peroxide
ionic liquid
label free
quantum dots
solid phase extraction
visible light
mass spectrometry
high resolution
tandem mass spectrometry
simultaneous determination