A sterically congested 1,2-diphosphino-1'-boryl-ferrocene: synthesis, characterization and coordination to platinum.
Emmanuel LerayerPatrice RenautJulien RogerNadine PirioHélène CatteyPaul Fleurat-LessardMaxime BoudjelelStéphane MassouGhenwa BouhadirDidier BourissouJean-Cyrille HiersoPublished in: Dalton transactions (Cambridge, England : 2003) (2019)
A new class of tritopic ferrocene-based ambiphilic compounds has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformational constraints, as is apparent from XRD and NMR data, but does not prevent the chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.