Efficient Broadband Near-Infrared Emission from Lead-Free Halide Double Perovskite Single Crystal.
Gangyi ZhangDeyin WangBibo LouChong-Geng MaAndries MeijerinkYuhua WangPublished in: Angewandte Chemie (International ed. in English) (2022)
Ultra-broadband near-infrared (NIR) luminescent materials are the most important component of NIR light-emitting devices (LED) and are crucial for their performance in sensing applications. A major challenge is to design novel NIR luminescent materials to replace the traditional Cr 3+ -doped systems. We report an all-inorganic bismuth halide perovskite Cs 2 AgBiCl 6 single crystal that achieves efficient broadband NIR emission by introducing Na ions. Experiments and density functional theory (DFT) calculations show that the NIR emission originates from self-trapped excitons (STE) emission, which can be enhanced by weakening the strong coupling between electrons and phonons. The high photoluminescence quantum efficiency (PLQY) of 51 %, the extensive full width at half maximum (FWHM) of 270 nm and the stability provide advantages as a NIR luminescent material. The single-crystal-based NIR LED demonstrated its potential applications in NIR spectral detection as well as night vision.
Keyphrases
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- fluorescence imaging
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