Copper and silver heterometallic iodoantimonates: structure, thermal stability, and optical properties.

Seven heterometallic iodoantimonates with the general formula (Cat) 2 {[Sb 2 M 2 I 10 ]} (M = Cu(I) (1-6), Ag(I) (7)) were prepared. X-ray diffraction data indicate that these compounds are the first Sb(III) representatives of the structural type previously known only for heterometallic iodobismuthates(III). In 3 and 4, halogen-substituted cations form halogen bonds with the heterometallic halometalate chain. 1-7 show prominent thermal stability. The estimated optical band gaps lie between 2.16 and 2.40 eV. As in heterometallic iodobismuthates, incorporation of Cu + rather than Ag + provides a much lower band gap.