Polyvinyl Alcohol-Citric Acid: A New Material for Green and Efficient Removal of Cationic Dye Wastewater.

The citric acid (CA) cross-linked polyvinyl alcohol (PVA) adsorbent, PVA-CA, was efficiently synthesized and its application to the removal of dyes in water, particularly the cationic dye, methylene blue (MB), was thoroughly investigated. The morphologies and physiochemical characteristics of PVA-CA were fully characterized by SEM, FT-IR, XRD, TGA, BET, and XPS. The effects of contact time, adsorbent dosage, MB concentration, solution pH, and temperature on the adsorption performance were compared using controllable methods. The maximum adsorption capacity of PVA-CA was 709.86 mg g -1 and the removal rate remained high through several adsorption-desorption cycles, demonstrating that such a composite absorbent has a good adsorption performance and recoverability. Further analysis by the density functional theory (DFT) showed that van der Waals interactions, electrostatic interactions and hydrogen bonding interactions between PVA-CA and MB played significant roles in the adsorption mechanism.