Lanthanide-Nitronyl Nitroxide Chains Derived from Multidentate Nitronyl Nitroxides.

Juan SunZan SunLi-Cun Li Jean-Pascal Sutter

Published in: Inorganic chemistry (2018)

Unprecedented lanthanide (Ln)-radical loop-chain coordination polymers were achieved using multidentate pyridyl- or triazole- substituted nitronyl nitroxide ligands. Their magnetic units consist of ferromagnetic [Ln2Radical] moieties, leading for the dysprosium(III) derivatives to slow relaxation of magnetization, which was found to be dependent on the heterocyclic ligands.

Keyphrases

single molecule
molecular docking
metal organic framework
room temperature
energy transfer
transcription factor
molecularly imprinted
mass spectrometry
molecular dynamics simulations