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Synthesis and Electro-Optical Property of Green Fluorescent Emitter Based on Anthracene Core and Optimized Side Groups.

Seunghyun KimSeokwoo KangJongwook Park
Published in: Journal of nanoscience and nanotechnology (2021)
New green emitter is designed and synthesized by selecting anthracene having high photoluminescence quantum yield (PLQY) and diphenylamine side group substituted methyl and t-butyl group: N9,N10-bis(5-(tert-butyl)-2-methylphenyl)-N9,N10-bis(2,4-dimethylphenyl)anthracene-9,10-diamine (3Me-1Bu-TPADA). Photophysical, electrochemical, and electroluminescent (EL) properties of 3Me-1Bu-TPADA were investigated. The maximum photoluminescence (PL) emission wavelengths of 3Me-1Bu-TPADA in solution and in a film were 528 nm and 531 nm, respectively. 3Me-1Bu-TPADA has excellent thermal properties with glass transition temperatures (Tg) of 110 °C, melting temperatures (Tm) of 217 °C of, and degradation temperature (Td) of 330 °C. 3Me-1Bu-TPADA was used as an emitting layer in non-doped devices: ITO/2-TNATA (60 nm)/NPB (15 nm)/3Me-1Bu-TPADA (30 nm)/Alq₃ (30 nm)/LiF (1 nm)/Al (200 nm). The 3Me-1Bu-TPADA device showed luminance efficiency of 6.05 cd/A, EQE of 2.68% at 10 mA/cm².
Keyphrases
  • light emitting
  • photodynamic therapy
  • quantum dots
  • ionic liquid
  • molecular dynamics
  • room temperature
  • highly efficient
  • liquid chromatography