Electrochemical Hydrogen Peroxide Synthesis from Selective Oxygen Reduction over Metal Selenide Catalysts.

Se-based nanoalloys as an emerging class of metal chalcogenide with tunable crystalline structure, component distribution, and electronic structure have attracted considerable interest in renewable energy conversion and utilization. In this Letter, we report a series of nanosized M-Se catalysts (M = Cu, Ni, Co) as prepared from laser ablation method and screen their electrocatalytic performance for onsite H 2 O 2 generation from selective oxygen reduction reaction (ORR) in alkaline media. A flexible control on 2e - /4e - ORR pathway has been achieved by engineering the alloying component. Moreover, through a feedback loop between theory and experiment an optimized scaling relationship between oxygenated ORR intermediates has been discovered on cubic Cu 7.2 Se 4 nanocrystals, that is, the ensemble effect of isolated Cu component destabilizes O* binding while the ligand effect of Se to Cu fine-tunes the binding strength of OOH*, leading to a superb H 2 O 2 selectivity above 90% over a wide potential window even after 1400 potential cycles.