The Divergent Reactivity of Lactones Derived from Butadiene and Carbon Dioxide in Macromolecular Synthesis.

The catalytic conversion of carbon dioxide and 1,3-butadiene into unsaturated lactone monomers provides an efficient route for converting sustainable carbon feedstocks into novel macromolecules. The chemical reactivity of this monomer is reviewed in order to highlight the many viable mechanistic pathways. Polymerization strategies, monomer alterations, and post-polymerization modifications are covered. The polymerization methods include radical, coordination, conjugate addition, ring-opening, olefin metathesis, and thiol-ene chemistries. Materials derived from these processes possess a wide range of function including responsiveness, degradability, adhesion, recyclability, and self-assembly. These aspects along with the advances in polymer chemistry that make them possible are discussed, along with a perspective on the future directions of the field.