Double spin crossovers: a new double salt strategy to improve magnetic and memory properties.
Wasinee PhonsriBarnaby A I LewisGuy N L JamesonKeith S MurrayPublished in: Chemical communications (Cambridge, England) (2019)
The structural, magnetic and Mössbauer spectral properties of a double salt, mixed-valent material, [FeII(3,5-Me2TPM)(TPM)][FeIII(azp)2]ClO4·2MeCN, 1, reveal spin transitions occur at both the metal sites, with hysteresis, indicative of 1 being a double spin crossover material.