Novel Green Reversible Humidity-Responsive Hemiaminal Dynamic Covalent Network for Smart Window.

Recently, smart windows have attracted widespread attention on account of their unique features, yet traditional smart windows still rely on external energy support to accomplish dynamic reversible switching, which not only confines usage but also causes waste of energy. For this purpose, we have prepared hemiaminal dynamic covalent network (HDCN) film with outstanding flexibility and strength by a simple and low-cost method, in which the modulus is 206.28 MPa and the elongation at break is 39.02%. Additionally, the transition from a transparent to an opaque state is achieved when the film is stimulated by humidity, and the dynamic transformation of the film to different phases of transparency is obtained when the film is exposed to different relative humidities (60-99%). Most importantly, HDCN film fulfills the modern green requirements and enables complete dissolution in a certain mildly acidic solution, avoiding environmental pollution when the material is discarded due to loss of function. The dynamic tunability of HDCN film demonstrates great advantages and potential in smart windows and anticounterfeiting.