Electrophoretic Co-deposition of Polyetheretherketone and Graphite Particles: Microstructure, Electrochemical Corrosion Resistance, and Coating Adhesion to a Titanium Alloy.

The present study explores the possibilities of fabricating a graphite/polyetheretherketone (PEEK) composite coating on a Ti-6Al-4V titanium alloy through duplex treatment consisting of electrophoretic deposition (EPD) and heat treatment. It has been found that the electrophoretic co-deposition of graphite and PEEK microparticles can be performed from environmentally-friendly pure ethanolic suspensions. Zeta potential measurements and a study of the interaction between both particle types with the use of transmission electron microscopy allowed potential mechanisms of particle co-deposition to be indicated. Microstructure characterization was performed on macro-, micro- and nanoscale using visible light microscopy, X-ray diffractometry and electron microscopy. This allowed the coating homogeneity and distribution of graphite particles in the polymer matrix to be described. Graphite particles in the form of graphene nanosheet packages were relatively evenly distributed in the coating matrix and oriented parallel to the coating surface. The heat-treated coatings showed high scratch resistance and no adhesive type destruction was observed, but they were highly susceptible to deformation. The corrosion measurements were performed with use of electrochemical techniques like open circuit potential and linear sweep voltamperometry. The coated alloy indicated better electrochemical corrosion resistance compared with the uncoated alloy. This work showed the high versatility of the electrophoretic co-deposition of graphite and PEEK particles, which combined with post-EPD heat treatment allows composite coatings to be fabricated with controlled distribution of graphite particles.