Selective electrochemical CO 2 conversion with a hybrid polyoxometalate.
Satoshi KuramochiJamie M CameronTomoya FukuiKieran D JonesStephen P ArgentShinpei KusakaRyo ShiraishiYusuke TamakiTaiki YatsuTakuya ShigaOsamu IshitaniH Hiroki OshioGraham N NewtonPublished in: Chemical communications (Cambridge, England) (2023)
A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO 2 to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.