Di- and trinuclear sandwich complexes of a cross-conjugated fulvene.

Eiji KudoYuki ObaKoji YamamotoTetsuro Murahashi

Published in: Dalton transactions (Cambridge, England : 2003) (2023)

We report di- and trinuclear palladium sandwich complexes of cross-π-conjugated fulvenes. Structural and theoretical analysis revealed that a fulvene sandwich framework holds a metal-metal bonded moiety, where the dinuclear and trinuclear bonds feature strong donation and back-donation, respectively. The trinuclear fulvene sandwich complex undergoes a unique reversible extrusion of a Pd atom from inside to outside the sandwich framework.

Keyphrases

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